In situ Raman spectroscopic study towards the growth and excellent HER catalysis of Ni/Ni(OH)2 heterostructure

The electrochemical water splitting to produce H₂ in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)₂ heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)₂ heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)₂ amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)₂ interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H₂-evolving current density of 10 mA/cm² and 153 mV at 100 mA/cm², as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)₂ heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)₂ interface reducing the energy barrier of H1 adsorption thus promoting the HER performance.     

Mapping Sentiments to Themes of Customer reactions on Social Media during a Security Hack: A Justice Theory Perspective

As social media continues to transform firm–customer interactions, firms must leverage customer reactions to generate actionable insights, especially in contexts (e.g., crisis events) where customer reactions are critical. Using the justice theory, we categorize customer reactions of two firms, Home Depot and Target, during the time-frame of a security hack to understand key themes/topics. We then map the themes/topics to customer sentiments in those reactions. We found that customers associate justice with simple procedures than the experience of dealing with the firm. In addition, it is critical for firms to carefully assess and control customer sentiments on social media during crisis events.     

The phase change thermoelastic analysis of biological tissue with variable thermal properties during cryosurgery

Abstract

In this work, the coupling phase change heat transfer process and thermal stress behavior of biological tissue during cryosurgery are studied in the context of a generalized thermoelastic theory. The nonlinear governing equations are constructed while considering the variable thermal properties and solved by a time-domain finite element method based on the effective heat capacity formulation. A 2-D tumor and normal tissue model is adopted for simulating the freezing process in cryosurgery. The effects of temperature-dependent thermal properties and relaxation time on the responses of biological tissue are discussed and illustrated graphically.     

矿井内因火灾的安全评价研究--基于熵值法和突变理论

针对矿井内因火灾的突发性、不确定性和高危害性等特点,提出熵值法和突变理论相结合的矿井内因火灾安全评价方法。选取人、物、环境和管理4个方面的因素建立了4级共20个评价指标的矿井内因火灾安全评价指标体系,运用熵值法判断各个指标的权重,利用突变级数法计算突变级数值,避免了单一熵值法主观人为赋权的弊端。以陕西省红石岩煤矿为例,运用该评价方法对其进行了内因火灾安全评价,其评价结果符合该矿井的安全状况,验证了该评价方法的可行性、实用性。     

Impact of industrial virtual power plant on renewable energy integration

An industrial park is one of the typical energy consumption schemes in power systems owing to the heavy industrial loads and their abilities to respond to electricity price changes. Therefore, energy integration in the industrial sector is significant. Accordingly, the concept of industrial virtual power plant (IVPP) has been proposed to deal with such problems. This study demonstrates an IVPP model to manage resources in an eco-industrial park, including energy storage systems, demand response (DR) resources, and distributed energies. In addition, fuzzy theory is used to change the deterministic system constraints to fuzzy parameters, considering the uncertainty of renewable energy, and fuzzy chance constraints are then set based on the credibility theory. By maximizing the daily benefits of the IVPP owners in day-ahead markets, DR and energy storage systems can be scheduled economically. Therefore, the energy between the grid and IVPP can flow in both directions: the surplus renewable electricity of IVPP can be sold in the market; when the electricity generated inside IVPP is not enough for its use, IVPP can also purchase power through the market. Case studies based on three wind-level scenarios demonstrate the efficient synergies between IVPP resources. The validation results indicate that IVPP can optimize the supply and demand resources in industrial parks, thereby decarbonizing the power systems.     

新型阶梯式浅吃水单立柱浮式风机平台水动力分析

常规的单立柱式(Spar)风力发电机平台,在水深较浅区域工作时,结构本身受吃水限制,工作效果较差。常规Spar重心较低,具有良好的稳定性,但是由于它往往具有超过100 m的吃水,因此使其不能应用于中近海域(水深小于100 m)。可设计研究一种适用于中国东海不超过100 m水深的中近海域新型浮式风机平台以解决此问题。针对NREL 5MW风机能应用于100 m水深的情况,对50 m吃水的新型Spar(SJTU-S4)及其系泊系统进行了概念设计研究。利用商业软件建立水动力模型,进行数值仿真,同时设计缩比模型试验,在上海交通大学海洋工程国家重点实验室(SKLOE)进行水动力性能测试。结果表明,本文研究的新阶梯式浅吃水单立柱浮式风机平台在100 m水深、多种海洋波浪环境下,通过试验和仿真验证,能够具有良好的运动响应,为风机提供较好的工作条件。     

Assessing cloud computing value in firms through socio-technical determinants

While cloud computing is touted as a promising information technology advancement, predictions of its value are inconclusive. This research investigates the impact of cloud computing within-firm and across-firm. Drawing on the resource-based view and sociotechnical theory, technical attributes and social attributes of cloud computing are identified to impact firm performance via primary and support use. Results from data collected from 513 firms show varying effects of technical and social attributes in primary use and support use, which help create value and better performance. Such effects also are found to differ between firms in service and manufacturing sectors.     

Fourier Analysis of Serial Dependence Measures

Classical spectral analysis is based on the discrete Fourier transform of the autocovariances. In this article we investigate the asymptotic properties of new frequency‐domain methods where the autocovariances in the spectral density are replaced by alternative dependence measures that can be estimated by U‐statistics. An interesting example is given by Kendall's τ, for which the limiting variance exhibits a surprising behavior.     

Bridging the critical interface: Ambidextrous innovation for water provision in Nairobi's informal settlements

This article examines innovation activities in water infrastructure in Nairobi, Kenya. The focus is on efforts by Nairobi City Water and Sewerage Corporation (NCWSC) to provide water services to the inhabitants in the informal areas of the city using an automated vending machine, or Pre-Paid Dispenser (PPD). In this study, we investigate what happens when a regime actor like NCWSC tries to implement an ambidextrous (two-handed) strategy: managing the existing system according to conventional practice and at the same time innovate in new technical solutions and business models to cater for unconnected users.Besides presenting our results, our aim in this article is also to introduce a research strategy for innovation studies in infrastructural systems in low-income urban areas. Three interconnected parts stand out as our contribution:First, we present a novel conceptual framework, by adding ideas from innovation studies to the Large Technical Systems approach. We investigate how regime actors can innovate to provide water to unconnected users, without expanding the system in a traditional way.Second, we propose a novel method for analysing and understanding innovation on the margins of the infrastructural system, or in our terms, innovation in the critical interface. Central to our method is, through empirical observation, to identify misalignment between the innovation (PPD) and contextual factors at the local level, where the innovation is implemented (interface misalignment), and misalignment between the innovation and the existing water regime (internal misalignment). We use a qualitative method and results forms as a basis for further research and starting point for regime actors in search of an improved ambidextrous strategy.Third, we analyse the innovation process per se. In the Nairobi case, we assess the ambidextrous innovation strategy, and claim that the PPD functions as an adapter in the critical interface, enabling the regime actors to operate in an environment of misalignment.